全文获取类型
收费全文 | 268篇 |
免费 | 7篇 |
专业分类
化学 | 178篇 |
晶体学 | 4篇 |
力学 | 5篇 |
数学 | 15篇 |
物理学 | 73篇 |
出版年
2021年 | 1篇 |
2019年 | 1篇 |
2018年 | 3篇 |
2016年 | 5篇 |
2015年 | 3篇 |
2014年 | 3篇 |
2013年 | 13篇 |
2012年 | 14篇 |
2011年 | 20篇 |
2010年 | 6篇 |
2009年 | 9篇 |
2008年 | 10篇 |
2007年 | 12篇 |
2006年 | 18篇 |
2005年 | 10篇 |
2004年 | 10篇 |
2003年 | 15篇 |
2002年 | 12篇 |
2001年 | 5篇 |
2000年 | 3篇 |
1999年 | 5篇 |
1998年 | 8篇 |
1997年 | 3篇 |
1996年 | 5篇 |
1995年 | 3篇 |
1994年 | 4篇 |
1993年 | 2篇 |
1992年 | 3篇 |
1991年 | 8篇 |
1990年 | 4篇 |
1989年 | 5篇 |
1988年 | 2篇 |
1986年 | 4篇 |
1985年 | 1篇 |
1984年 | 5篇 |
1983年 | 2篇 |
1982年 | 4篇 |
1981年 | 1篇 |
1980年 | 5篇 |
1979年 | 6篇 |
1978年 | 7篇 |
1977年 | 2篇 |
1976年 | 3篇 |
1975年 | 2篇 |
1974年 | 2篇 |
1973年 | 4篇 |
1972年 | 1篇 |
1969年 | 1篇 |
排序方式: 共有275条查询结果,搜索用时 593 毫秒
11.
Experimental and computational studies were performed to understand the electronic structure of ternary perovskites (ASnO(3), A = Ca, Sr, Ba, Cd), pyrochlores (RE(2)Sn(2)O(7), RE = Y, La, Lu; Cd(2)Sb(2)O(7)), and defect pyrochlore oxides (Ag(2)Sb(2)O(6)) containing the main group ions Sn(4+) and Sb(5+). In all compounds, the lowest energy states in the conduction band arise primarily from the antibonding Sn/Sb 5s-O 2p interaction. In the alkaline-earth stannate perovskites (BaSnO(3), SrSnO(3), and CaSnO(3)) the conduction bandwidth decreases strongly in response to the octahedral tilting distortion triggered by the decreasing size of the alkaline-earth cation. This in turn leads to a corresponding increase in the band gap from 3.1 eV in BaSnO(3) to 4.4 eV in CaSnO(3). The band gap of CdSnO(3) is relatively small (3.0 eV) considering the large octahedral tilting distortion. The origin of this apparent anomaly is the mixing between the empty Cd 5s orbitals and the antibonding Sn 5s-O 2p states. This mixing leads to a widening of the conduction band and a corresponding decrease in the band gap. The participation of the normally inert A-site cation in the electronic structure near the Fermi level can be considered an inductive effect, as it utilizes substitution on the A-site to directly modify the electronic structure of the SnO(3)(2)(-) framework. While the pyrochlore structure is more complicated, the energy level and width of the lowest energy conduction band can be analyzed in a manner similar to that utilized on the perovskite structure. The Sn-O-Sn and Sb-O-Sb bonds are highly distorted from linear geometry in pyrochlore, leading to a relatively narrow conduction band and a wide band gap. In Cd(2)Sb(2)O(7) and Ag(2)Sb(2)O(6) the Cd(2+) and Ag(+) ions exhibit a strong inductive effect that widens the conduction band and lowers the band gap significantly, very similar to the effect observed in the perovskite form of CdSnO(3). 相似文献
12.
Mizoguchi TJ Kuzelka J Spingler B DuBois JL Davydov RM Hedman B Hodgson KO Lippard SJ 《Inorganic chemistry》2001,40(18):4662-4673
Two compounds, [Fe2(mu-OH)(mu-Ph4DBA)(TMEDA)2(OTf)] (4) and [Fe2(mu-OH)(mu-Ph4DBA)(DPE)2(OTf)] (7), where Ph4DBA(2-) is the dinucleating bis(carboxylate) ligand dibenzofuran-4,6-bis(diphenylacetate), have been prepared as synthetic models for the dioxygen-binding non-heme diiron protein hemerythrin (Hr). X-ray crystallography reveals that, in the solid state, these compounds contain the asymmetric coordination environment found at the diiron center in the reduced form of the protein, deoxyHr. M?ssbauer spectra of the models (4, delta = 1.21(2), DeltaE(Q) = 2.87(2) mm s(-1); 7, delta(av) = 1.23(1), DeltaE(Qav) = 2.79(1) mm s(-1)) and deoxyHr (delta = 1.19, DeltaE(Q) = 2.81 mm s(-1)) are also in good agreement. Oxygenation of the diiron(II) complexes dissolved in CH2Cl2 containing 3 equiv of N-MeIm (4) or neat EtCN (7) at -78 degrees C affords a red-orange solution with optical bands at 336 nm (7300 M(-1) cm(-1)) and 470 nm (2600 M(-1) cm(-1)) for 4 and at 334 nm (6400 M(-1) cm(-1)) and 484 nm (2350 M(-1) cm(-1)) for 7. These spectra are remarkably similar to that of oxyHr, 330 nm (6800 M(-1) cm(-1)) and 500 nm (2200 M(-1) cm(-1)). The electron paramagnetic resonance (EPR) spectrum of the cryoreduced, mixed-valence dioxygen adduct of 7 displays properties consistent with a (mu-oxo)diiron(II,III) core. An investigation of 7 and its dioxygen-bound adduct by extended X-ray absorption fine structure (EXAFS) spectroscopy indicates that the oxidized species contains a (mu-oxo)diiron(III) core with iron-ligand distances in agreement with those expected for oxide, carboxylate, and amine/hydroperoxide donor atoms. The analogous cobalt complex [Co2(mu-OH)(mu-Ph4DBA)(TMEDA)2(OTf)] (6) was synthesized and structurally characterized, but it was unreactive toward dioxygen. 相似文献
13.
Chetsumon Aparat Umeda Fusako Maeda Isamu Yagi Kiyohito Mizoguchi Tadashi Miura Yoshiharu 《Applied biochemistry and biotechnology》1998,(1):249-256
A photobioreactor was constructed using anchored polyurethane foam strips (1 x 1 x 40 cm) fixed onto a stainless-steel ring
to prevent flotation, as a biomass support material (BSM). This type of reactor was named a seaweed-type bioreactor. A filamentous
cyanobacterium, Scytonema sp. TISTR 8208, which produces a novel cyclic dodecapeptide antibiotic, was immobilized in seaweed-type
photobioreactor and cultivated with air containing 5% CO2 sparged at a gas flow rate of 250 mL/min under illumination at a light intensity of 200 μmol photon m-2s-1. The antibiotic produced in the seaweed-type photobioreactor was purified by HPLC and examined regarding its spectrum and
mode of action. The antibiotic effectively inhibited the growth of Gram-positive bacteria, pathogenic yeasts, and filamentous
fungi, but it had only a weak effect on Gram-negative bacteria. Scanning electron micrograph analysis showed that the most
characteristic change was swelling of the cells after exposure to the antibiotic. The antibiotic seems to alter the conformation
of the microbial cell membrane, thereby changing its permeability, leading to osmotic shock. 相似文献
14.
K. M. Nowak T. Ohta T. Suganuma J. Fujimoto H. Mizoguchi A. Sumitani A. Endo 《Opto-Electronics Review》2013,21(4):345-354
It was shown both theoretically and experimentally that nanosecond order laser pulses at 10.6 micron wavelength were superior for driving the Sn plasma extreme ultraviolet (EUV) source for nano-lithography for the reasons of higher conversion efficiency, lower production of debris and higher average power levels obtainable in CO2 media without serious problems of beam distortions and nonlinear effects occurring in competing solid-state lasers at high intensities. The renewed interest in such pulse format, wavelength, repetition rates in excess of 50 kHz and average power levels in excess of 18 kiloWatt has sparked new opportunities for a matured multi-kiloWatt CO2 laser technology. The power demand of EUV source could be only satisfied by a Master-Oscillator-Power-Amplifier system configuration, leading to a development of a new type of hybrid pulsed CO2 laser employing a whole spectrum of CO2 technology, such as fast flow systems and diffusion-cooled planar waveguide lasers, and relatively recent quantum cascade lasers. In this paper we review briefly the history of relevant pulsed CO2 laser technology and the requirements for multi-kiloWatt CO2 laser, intended for the laser-produced plasma EUV source, and present our recent advances, such as novel solid-state seeded master oscillator and efficient multi-pass amplifiers built on planar waveguide CO2 lasers. 相似文献
15.
Takayama K Arakida Y Dixit T Iwashita T Kono T Nakamura E Otsuka K Shimosaki Y Torikai K Wake M 《Physical review letters》2007,98(5):054801
We report an experimental demonstration of the induction synchrotron, the concept of which has been proposed as a future accelerator for the second generation of neutrino factory or hadron collider. The induction synchrotron supports a superbunch and a superbunch permits more charge to be accelerated while observing the constraints of the transverse space-charge limit. By using a newly developed induction acceleration system instead of radio-wave acceleration devices, a single proton bunch injected from the 500 MeV booster ring and captured by the barrier bucket created by the induction step voltages was accelerated to 6 GeV in the KEK proton synchrotron. 相似文献
16.
17.
Takashi Iwatsubo Toshio Masuoka Kensaku Mizoguchi 《Journal of Polymer Science.Polymer Physics》1994,32(1):1-6
Pervaporation of a water/alcohol mixture through a membrane which has ion-exchange capacity has been investigated. Theoretical equations are introduced which relate the degree of ionic dissociation of the polymer to quantities of water and alcohol dissolved in the polymer. From these equations, an equation for selective dissolution R is derived which does not contain an explicit term for ionic dissociation. Dissociation affects selective dissolution only by changing the degree of swelling of the polymer. Reformulating R asymptotically obtains a reciprocal relationship between permselectivity and permeability for a water-selective membrane. Experiments to check the validity of the relationship have been carried out using chitosan membranes neutralized by several acids. The effect of degree of neutralization also has been investigated. Results can be well understood on the supposition that ionic dissociation depends upon the water/alcohol composition, the kind of acid, and the degree of neutralization. Experimental results indicate that the reciprocal relationship is maintained over an appropriate range of feed compositions which confirm the validity of the theoretical equations for the swelling equilibrium of an ionic membrane. © 1994 John Wiley & Sons, Inc. 相似文献
18.
19.
Nuclear magnetic relaxation times, T1 and T2 are measured in dilute Au-V alloys for 1–300 K. A value for T1T = 17.0 ± 0.5 msK is obtained. 相似文献
20.
Yukiji Shimojima Hiroshi Hayashi Tadaaki Ooka Mitsuru Shibukawa Yoichi Iitaka 《Tetrahedron letters》1982,23(51):5435-5438
The structures of a novel gastroprotective substance AI-77-B and its analogues AI-77-C, D, F and G, which are produced by Bacillus pumilus, are described. Five of the asymmetric centers of AI-77-B have S absolute stereochemistry confirmed by X-ray in combination with chemical studies. 相似文献